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Various indicators of resource scarcity and methods for extrapolating resource availability are examined for phosphorus. These include resource lifetime, and trends in resource price, ore grade and discovery rates, and Hubbert curve extrapolation. Several of these indicate increasing scarcity of phosphate resources. Calculated resource lifetime is subject to a number of caveats such as unanticipated future changes in resource discovery, mining and beneficiation technology, population growth or per-capita demand. Thus it should be used only as a rough planning index or as a relative indicator of potential scarcity. This paper examines the uncertainty in one method for estimating available resources from historical production data. The confidence intervals for the parameters and predictions of the Hubbert curves are computed as they relate to the amount of information available. These show that Hubbert-type extrapolations are not robust for predicting the ultimately recoverable reserves or year of peak production of phosphate rock. Previous successes of the Hubbert curve are for cases in which there exist alternative resources, which is not the situation for phosphate. It is suggested that data other than historical production, such as population growth, identified resources and economic factors, should be included in making such forecasts.
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http://dx.doi.org/10.1016/j.chemosphere.2011.01.052 | DOI Listing |
Chem Commun (Camb)
September 2025
School of Chemistry and Life Resources, Renmin University of China, Beijing, 100872, China.
Through molecular dynamics simulations of imidazolium-based ionic liquid-water mixtures, it was found that the trace water leads to an anomalous non-monotonic change in the diffusion coefficients of ionic liquid, characterized by an initial decrease followed by an increase. Hydrogen bond analysis revealed that this unusual trend is governed by the weighted hydrogen bond lifetime, reflecting the stability of the hydrogen-bond network, rather than simply the number or energy of hydrogen bonds.
View Article and Find Full Text PDFJ Phys Chem B
September 2025
Key Laboratory of Advanced Light Conversion Materials and Biophotonics, School of Chemistry and Life Resources, Renmin University of China, Beijing 100872, China.
Light-harvesting complex IIs (LHCIIs) are the major antenna in higher plants, balancing light capture through photoprotection. While it naturally forms trimers, stress conditions can induce monomerization, altering pigment interactions. Here, we explored how molecular oxygen affects triplet excited-state dynamics in LHCII monomers using time-resolved transient absorption spectroscopy under aerobic and anaerobic conditions.
View Article and Find Full Text PDFBMC Pregnancy Childbirth
September 2025
Department of Psychology, Reykjavik University, Reykjavík, Iceland.
Background: One in three women worldwide will experience physical and/or sexual violence in their lifetime, and pregnancy is a risk factor for domestic violence. Recent studies have identified global stressors, such as the COVID-19 pandemic, as being connected to an increased prevalence of domestic violence. The aim of the present study was threefold: Firstly, to investigate the prevalence of DV among pregnant women during the COVID-19 pandemic in Iceland.
View Article and Find Full Text PDFJ Affect Disord
September 2025
Department of Counseling, College of Education, Health, and Human Science, University of Nebraska Omaha, United States of America. Electronic address:
Background: Adverse Childhood Experiences (ACEs) and Positive Childhood Experiences (PCEs) play critical roles in adolescent mental health, influencing onset and recovery. Informed by the Social-Ecological Risk and Protective Factors framework, the current study examines ACEs as barriers and PCEs as facilitators in recovery from anxiety and depression. We used continuous score and categorical subgroup models to capture both linear and potential threshold effects.
View Article and Find Full Text PDFLuminescence
September 2025
Department of Computational and Applied Mechanics, Federal University of Juiz de Fora, Juiz de Fora, Brazil.
Rare-earth ions (REIs), especially trivalent lanthanides (Ln ), are central to photonic technologies due to sharp intra-4f transitions, long lifetimes, and host-insensitive emission. However, modeling REIs remains challenging due to localized 4f orbitals, strong electron correlation, and multiplet structures. This review summarizes atomistic modeling strategies combining quantum chemistry and machine learning (ML).
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