Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 197
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 197
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 271
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3165
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 597
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 511
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 317
Function: require_once
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The influencing factors and kinetics of copper ions removal from aqueous solution by zero-valent iron (ZVI) was investigated, the mechanism of Cu2+ removal was analyzed using X-ray diffraction (XRD). The experimental results showed that ZVI had been turned out to be an effective tool for the removal of Cu2+ from aqueous solution. More than 99% of Cu2+ could be removed at an initial concentration of 300 mg/L by ZVI at the dosage of 1 g/L. The removal of Cu2+ in the first 30 min could be described by the first-order kinetic model with high correlation coefficient. The XRD analysis suggested that the mechanism for Cu2+ removal was mainly based on the redox reaction, which resulted in the formation of Cu2O qand CuO as the main reduced products of Cu2+.
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