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The propagation of 2D+1 wave packets in 1D band gap systems shows that the interplay of periodicity and nonlinearity leads to the spontaneous formation of fast and slow conical localized waves. Such nonlinear tunneling has features that differ on the two edges of the band gap and it is characterized by the competition of bullets and nonlinear X waves.
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http://dx.doi.org/10.1103/PhysRevLett.101.013601 | DOI Listing |
Discov Nano
September 2025
Henan Key Laboratory of Diamond Optoelectronic Materials and Devices, Key Laboratory of Integrated Circuit, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou, 450052, China.
A cost-effective and large-scale method for synthesizing ZnCoO nanoflowers with surface oxygen vacancies as electrode materials for supercapacitors is presented. The existence of oxygen vacancies on the surface of the ZnCoO nanoflowers has been confirmed through X-ray photoelectron spectroscopy (XPS). The energy bands and density of states (DOS) of ZnCoO are examined using density functional theory, revealing that treatment with NaBH reduces the band gap of ZnCoO while increasing the DOS near the Fermi level compared to pristine ZnCoO.
View Article and Find Full Text PDFInorg Chem
September 2025
Departmento de Química Inorgánica, Universidad de Valencia, C/Dr. Moliner 50, 46100 Burjasot, Valencia, Spain.
[Cu(3-bph)(PABA)(HO)] () (3-bph = ,'-bis(3-pyridylmethylene)hydrazine and PABA = -amino benzoate) is a pyridyl-N bridging Cu coordination polymer, and PABA acts as a carboxylate-O donor forming a square pyramidal CuNO motif following a zigzag one-dimensional (1D) lattice. The shows weak antiferromagnetic coupling ( = -0.196(1) cm), and emission appears at 352 nm (λ = 293 nm), which is selectively quenched by Fe via the FRET mechanism.
View Article and Find Full Text PDFNanoscale
September 2025
St. Petersburg State University, 199034 St. Petersburg, Russia.
Using angle-resolved photoemission spectroscopy (ARPES) with spin resolution, scanning tunneling microscopy/spectroscopy (STM/STS) and density functional theory (DFT) methods, we study the electronic structure of graphene-covered and bare Au/Co(0001) systems and reveal intriguing features, arising from the ferrimagnetic order in graphene and the underlying gold monolayer. In particular, a spin-polarized Dirac-cone-like state, intrinsically related to the induced magnetization of Au, was discovered at point. We have obtained a good agreement between experiment and theory for bare and graphene-covered Au/Co(0001) and have proven that both Au ferrimagnetism and the Dirac-cone-like band are intimately linked to the triangular loop dislocations present at the Au/Co interface.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, P.R. China.
Metal halide perovskites have garnered significant attention due to their exceptional photoelectric properties. The alkali metal doping strategy has been demonstrated to effectively modulate grain size, control crystallization kinetics, and adjust band gap characteristics in perovskite. This study employs the first-principles calculations to reveal that the selection of alkali metal species and their corresponding doping methodologies exert markedly distinct influences on both the electronic properties and ion migration kinetics of CsPbBr perovskites.
View Article and Find Full Text PDFJ Mater Chem B
September 2025
Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China.
The effect of sonocatalysis on anticancer treatment is always restricted by rapid recombination of charge and low utilization of the ultrasonic cavitation effect. Herein, cobalt-doped prussian blue (PB) nanocubes were synthesized, and then they were etched by acidic solution to obtain amorphous Co-FePB@1h with abundant defects including: Fe/Co defects, Fe-(CN) vacancies, and dangling bonds. Both doping and defect engineering contribute to decreasing the band gap and promoting charge separation.
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