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Composites consisting of Al-Zn/Al2O3 have been synthesized using high energy mechanical milling. High energy ball milling increases the sintering rate of the composite powder due to increased diffusion rate. Owing to the finer microstructure, the hardness of the sintered composite produced by using the mechanically milled nanocomposite powder is significantly higher than that of the sintered composite produced by using the as-mixed powder. The mean crystallite size of the matrix has been determined to be 27 nm by Scherrer equation using X-ray diffraction data. The powders have been characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and differential thermal analysis (DTA). The effect of high-energy ball milling and subsequent annealing on a mixture of Al and ZnO has also been investigated. DTA result show that the reaction temperature of Al-ZnO decreases with the increase in the ball milling time.
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http://dx.doi.org/10.1166/jnn.2007.753 | DOI Listing |
Chem Commun (Camb)
September 2025
LCC, CNRS & Université de Toulouse (UPS, INP), 31077 Toulouse, France.
Ball milling experiments were conducted on spin crossover (SCO) powder and SCO@polyurethane composite samples. The study reveals that the presence of the TPU matrix acts as a shield for the SCO particles upon grinding, precluding their deactivation. This result is encouraging for the integration of SCO materials into devices.
View Article and Find Full Text PDFBr J Anaesth
September 2025
Department of Anaesthesiology, Amsterdam University Medical Centers, location 'AMC', Amsterdam, The Netherlands; Department of Anaesthesiology, The Netherlands Cancer Institute-Antoni van Leeuwenhoek Hospital, Amsterdam, The Netherlands.
Background: The relationship between intraoperative end-tidal CO (etCO) levels and postoperative outcomes remains unclear. We conducted a post hoc analysis of two randomised trials in adults undergoing major surgery under general anaesthesia.
Methods: We re-analysed individual participant data comparing high or low positive end-expiratory pressure with low tidal volume intraoperative ventilation using a merged database derived from two randomised trials in non-obese (PROVHILO: ISRCTN70332574) and obese (PROBESE: NCT02148692) patients.
Sci Total Environ
September 2025
School of Civil Engineering, Sichuan Agricultural University, Chengdu, 611830, China; Sichuan Higher Education Engineering Research Center for Disaster Prevention and Mitigation of Village Construction, Sichuan Agricultural University, Chengdu, 611830, China.
Biochar has emerged as a promising soil amendment for improving soil quality and mitigating environmental impacts, such as nutrient leaching. This study evaluated the impacts of ball-milled bamboo nano-biochar on water infiltration dynamics, retention capacity, and nitrogen‑phosphorus leaching in sandy loam soil using controlled column experiments and leaching experiments with five application doses alongside bulk biochar and untreated controls. Experimental results demonstrated that nano-biochar application significantly enhanced soil water retention capacity compared to the raw soil.
View Article and Find Full Text PDFCharged hadron elliptic anisotropies (v_{2}) are presented over a wide transverse momentum (p_{T}) range for proton-lead (pPb) and lead-lead (PbPb) collisions at nucleon-nucleon center-of-mass energies of 8.16 and 5.02 TeV, respectively.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
Inorganic Chemistry I Institute, Ruhr-Universität Bochum, Universitätsstrasse 150, 44801 Bochum, Germany.
Herein, we report a solid-state polycyclotrimerization of 1,4-diethynylbenzene using mechanochemical activation in a ball mill, yielding a highly porous and hydrophobic hyperbranched polymer (HBP) with a specific surface area of up to 570 m g. The reaction, catalyzed by Fe(hmds) and conducted under solvent-free conditions, was optimized by varying milling time and frequency. This method enables the efficient synthesis of insoluble, porous organic polymers with high yields (up to 95%) and offers an environmentally friendly alternative to traditional solution-based polymerizations.
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