98%
921
2 minutes
20
A gigawatt laser-induced Coulomb explosion has been observed in carbon disulphide (CS(2)) clusters generating energetic, multiply charged [C](m+) (m = 1-4) and [S](n+) (n = 1-6) atomic ions of carbon and sulphur. The Coulomb explosion shows wavelength dependence. Comparison of these results with our earlier work shows that the polarizability and dipole moment might help in energy absorption from the laser field but they are not mandatory conditions for this low-intensity Coulomb explosion. The results show that in a field of 10(9) W/cm(2), absorption of 266 and 355 nm laser radiation by CS(2) clusters leads to multiphoton dissociation/ionization whereas at 532 nm the whole cluster explodes generating multiply charged atomic ions.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1002/rcm.3127 | DOI Listing |
Commun Chem
September 2025
Department of Chemistry, University of Oxford, The Chemistry Research Laboratory, Oxford, UK.
Although the photochemistry of nitrobenzene has been extensively studied, the assignment of fragmentation channels and their specific dynamics remains challenging. Here the photochemistry of nitrobenzene following 240 nm excitation into its S excited singlet state is investigated by femtosecond laser-induced ionization using an intense 800 nm pulse, coupled with time-resolved Coulomb explosion imaging and covariance mapping. We assign photochemical channels by observing correlations between the molecular fragment ions of the associated product pairs, enabling the time-resolved dynamics of channels leading to NO, NO, and CHNO to be fully characterized.
View Article and Find Full Text PDFChem Commun (Camb)
August 2025
DST Unit of Nanoscience (DST UNS) & Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology Madras (IITM), Chennai 600036, India.
The recent discovery of the rapid conversion of micron-sized common minerals to nanoparticles in charged water microdroplets has attracted significant attention. Here, we studied this micro-to-nano transition as a function of applied electric potential and tip-to-substrate distance using high-resolution transmission electron microscopy (HRTEM). Our observations revealed that the fragmentation progresses through distinct stages, from larger particles to flower-like intermediates and finally to nanoparticles.
View Article and Find Full Text PDFScience
August 2025
European XFEL, Schenefeld, Germany.
Because of the Heisenberg uncertainty principle, the structure of a molecule fluctuates about its mean geometry, even in the ground state. Observing this fundamental quantum effect experimentally-particularly, revealing the collective nature of the structural quantum fluctuations-remains an unmet challenge for complex molecules. In this work, we achieved this for an 11-atom molecule by inducing its Coulomb explosion with an x-ray free-electron laser.
View Article and Find Full Text PDFEur Biophys J
July 2025
Department of Physics, University of Rome Tor Vergata and INFN, Via della Ricerca Scientifica 1, 00133, Rome, Italy.
The EuPRAXIA project is a European initiative aimed at developing groundbreaking, ultra-compact accelerator research infrastructures based on novel plasma acceleration concepts. The EuPRAXIA@SPARC_LAB facility, located in the Italian National Institute for Nuclear Physics-Frascati National Laboratory, will be the first operating Free Electron Laser facility of EuPRAXIA, based on an accelerator module driven by an electron bunch driver. The Free Electron Laser will produce ultra-short photon pulses in the soft X-ray region.
View Article and Find Full Text PDFJ Chem Phys
July 2025
2nd Liuxian Rd., Shenzhen, Guangdong 518000, China.
We present efficient and reliable molecular dynamics simulations of the photodissociation of dichloromethane, followed by Coulomb explosion. These simulations are performed by calculating trajectories on accurate potential energy surfaces of the low-lying excited states of the neutral dichloromethane molecule. The subsequent time-resolved Coulomb explosions are simulated on the triply charged ionic state, assuming Coulomb interactions between ionic fragments.
View Article and Find Full Text PDF