Design of a novel inherently chiral calix[4]arene for chiral molecular recognition.

Org Lett

Department of Applied Molecular Chemistry and High Technology Research Center, College of Industrial Technology, Nihon University, Narashino, Chiba, 275-8575, Japan.

Published: August 2007


Category Ranking

98%

Total Visits

921

Avg Visit Duration

2 minutes

Citations

20

Article Abstract

A newly designed inherently chiral calix[4]arene was synthesized and resolved to an optically pure form. Enantiomeric recognition ability of the chiral calix[4]arene was examined using 1H NMR experiments with mandelic acid. In addition, the chiral calix[4]arene was applied to asymmetric reactions, as an organocatalyst.

Download full-text PDF

Source
http://dx.doi.org/10.1021/ol071249pDOI Listing

Publication Analysis

Top Keywords

chiral calix[4]arene
16
inherently chiral
8
chiral
5
design novel
4
novel inherently
4
calix[4]arene
4
calix[4]arene chiral
4
chiral molecular
4
molecular recognition
4
recognition newly
4

Similar Publications