FeNiMn invar alloy was produced via the polyol process, employing a polyvinyl alcohol (PVA) solution in varying weight ratios (50% and 66% PVA), and carbonized at different temperatures in argon (Ar) atmosphere to create a magnetic core-shell structure of FeNiMn@C. The structural, morphological, and magnetic characteristics of the prepared material were analyzed using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Brunauer-Emmett-Teller (BET) method, Fourier-transform infrared spectroscopy (FTIR), and vibrating sample magnetometry (VSM). The carbonization process applied to these samples enhances their suitability for the adsorption of weakly polar or nonpolar organic molecules.
View Article and Find Full Text PDFDeclining water resources and their contamination with chemicals risk the aquatic environment. Therefore, this work was devoted to designing a magnetically recyclable photocatalyst suitable for water treatment, namely, a TiO /FeO@g-C composite. Different preparation conditions were investigated together with the corresponding characteristics.
View Article and Find Full Text PDFNanotechnologies have been advantageous in many sectors and gaining much concern due to the unique physical, chemical and biological properties of nanomaterials (NMs). We have surveyed peer-reviewed publications related to "nanotechnology", "NMs", "NMs water treatment", "NMs air treatment", and "NMs environmental risk" in the last 23 years. We found that most of the research work is focused on developing novel applications for NMs and new products with peculiar features.
View Article and Find Full Text PDFIn Egypt, pharmaceuticals consumption increased dramatically owing to the population growth and the unrestricted sale manner. Accordingly, the occurrence and fate of nine common pharmaceutical active compounds (PhACs) were scrutinized at a sewage treatment plant (STP) in Giza, Egypt. The levels of these PhACs were assessed in different the wastewater treatment stages and dewatered sludge phase using high-performance liquid chromatography coupled with photodiode arrays detector.
View Article and Find Full Text PDFGlass and glass-ceramic materials containing photoactive and magnetic crystalline phases were prepared from FeO and BiO using the conventional melt method. All samples were characterized in terms of formed phases, morphological analyses, optical properties, and magnetic properties. Formation of the photoactive tetragonal β- and body-centered cubic γ-BiO phases along with the magnetic BiFeO and FeO phases was revealed.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
September 2020
Membrane fouling is a common problem in membrane technology and causes detrimental effects for the applied membranes such as loss of integrity and productivity. Henceforward, we devoted this work to fabricate membranes that pose favored criteria in the direction of alleviating membrane fouling incidence. Herein, the fabricated membranes were traced via an assortment of both experimental and molecular modeling verifications to understand the mechanism of interaction.
View Article and Find Full Text PDFRecently, naturally occurring biopolymers have attracted the attention as potential adsorbents for the removal of water contaminants. In this work, we present the development of microcrystalline cellulose (MCC)-based nanogel grafted with acrylamide and acrylic acid in the presence of methylene bisacrylamide and potassium persulphate as a crosslinking agent and initiator, respectively. World-class facilities such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), surface analysis, field emission scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM) and zeta sizer were used to characterize the synthesized MCC based nanogel.
View Article and Find Full Text PDFThe drinking water industry is required to minimize DBPs levels while ensuring adequate disinfection. In this study, efficient and appropriate treatment scheme for the reduction of disinfection by-product (DBPs) formation in drinking water containing natural organic matter has been established. This was carried out by the investigation of different treatment schemes consisting of enhanced coagulation, sedimentation, disinfection by using chlorine dioxide/ozone, filtration by sand filter, or granular activated carbon (GAC).
View Article and Find Full Text PDFThis study focused on the use of spinel manganese-cobalt (Mn-Co) oxide, prepared by a solid state reaction, as a cathode catalyst to replace platinum in microbial fuel cells (MFCs) applications. Spinel Mn-Co oxides, with an Mn/Co atomic ratios of 0.5, 1, and 2, were prepared and examined in an air cathode MFCs which was fed with a molasses-laden synthetic wastewater and operated in batch mode.
View Article and Find Full Text PDFCiprofloxacin (CIP) is a famous synthetic chemotherapeutic antibiotic. It is widely found either in water or wastewater. In this study ciprofloxacin was photocatalytically degraded using commercial anatase titanium dioxide (TiO(2)) under simulated sunlight.
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