Chronic wounds are a foremost cause of death, affecting 6.5 million people annually. Traditional treatments, such as metal-based formulations and biomaterials, are ineffective due to their toxicity and the rising incidence of chronic wound cases, necessitating the advancement of new therapies for efficient wound healing.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2025
The development of high-performance anion exchange membranes (AEMs) remains a major challenge in commercializing alkaline fuel cells. Significant efforts have been directed toward enhancing the ionic conductivity, mechanical strength, and alkaline stability of AEMs. Among various strategies, modifying commercially available polymers has emerged as an effective and straightforward approach.
View Article and Find Full Text PDFTwo Schiff bases, ()-4-((2-chlorobenzylidene)amino)-1,5-dimethyl-2-phenyl-1,2-dihydro-3-pyrazol-3-one (4AAPOCB) and ()-4-((4-chlorobenzylidene)amino)-1,5-dimethyl-2-phenyl-1,2-dihydro-3-pyrazol-3-one (4AAPPCB), have been synthesized and grown as single crystals. Single-crystal X-ray diffraction analysis was employed to determine the crystal structure of the compounds, and the results suggest that the compounds crystallized into an orthorhombic crystal system having 222 and space groups, respectively. Further, the crystallinity of the compounds was analyzed by the PXRD technique.
View Article and Find Full Text PDFNovel organic charge transfer complex, m-xylylenediaminium-bis (p-toluenesulfonate) monohydrate (XDPTS) have been synthesized and crystallized to the triclinic system with space group P-1 and the lattice parameters obtained are a=9.9265(7) Å, b=9.9676(6) Å, c=13.
View Article and Find Full Text PDFA new hydrogen-bonded charge-transfer complex (CT) formed by the reaction between donor, 2,6-diaminopyridine and acceptor, 4-nitrophenylacetic acid in methanol at room temperature. The crystal was characterized by elemental analysis, IR, NMR spectroscopic studies and thermal studies. The elemental analysis of CT complex, obtained data revealed that the formation of 1:1 ratio CT complex was proposed.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
June 2015
A single crystal charge transfer (CT) complex, 2-aminopyridinium-4-methylbenzenesulfonate (APTS) was synthesized and recrystallized by slow solvent evaporation solution growth method at room temperature. The complex has been characterized with the elemental analysis, UV-visible, infrared (IR), (1)H and (13)C nuclear magnetic resonance (NMR) spectra. Thermogravimetric (TG) and differential thermal analysis (DTA) were reported the thermal behaviour of the complex.
View Article and Find Full Text PDFStudies concentration on hydrogen-bonded charge-transfer complex formed on the reaction between basic 2,3-dimethylquinoxaline with p-toluenesulfonic acid. The crystal was characterized by IR, NMR, thermal and elemental analysis. The crystal structure was deduced by single crystal X-ray diffraction studies which indicated that cation and anion are linked through strong N(+)-H---O(-) type of hydrogen bond.
View Article and Find Full Text PDFWe have developed an effective microwave assisted p-TsOH catalyzed synthesis of pyrido[2,3-a]carbazoles via a one pot reaction of ethanolamine and 1-chloro-2-formyl carbazoles. The structure has been characterized by spectroscopic methods. The electronic spectroscopic experimental evidence strongly showed that the compounds could interact with calf thymus DNA (CT-DNA) through intercalation with a binding constant value of 1.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2014
Carbazole picrate (CP), a new organic compound has been synthesized, characterized by various analytical and spectroscopic technique such as FT-IR, UV-Vis, (1)H and (13)C NMR spectroscopy. An orthorhombic geometry was proposed based on single crystal XRD study. The thermal stability of the crystal was studied by using thermo-gravimetric and differential thermal analyses and found that it was stable up to 170°C.
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