Supramolecular functional helical superstructures are typical structures exhibiting many fascinating properties and performances. In nature, cholesteric liquid crystals (CLCs) are self-assembled soft helical superstructures that display orientation-dependent features of supramolecular helical architectures and have potential scientific applications. The most intriguing applications of CLCs primarily depend on the various orientations of their helical axis.
View Article and Find Full Text PDFFresnel zone plates (FZPs) are widely used in integrated optical systems to meet new cutting-edge demands for photonic integration and device miniaturizing. However, their use in applications of cross-scale fabrication still faces several obstacles, such as low efficiency, fixed focal length, single wavelength, large size, and complicated fabrication. Here, we first examine a novel adaptive focal length in white light focusing by using reflective-type and phase-only spatial light modulator (RLC-SLM) based on a liquid crystal on silicon.
View Article and Find Full Text PDFA polarization-insensitive liquid crystal (LC) Fresnel lens is developed with binary LC configurations of 90°-twisted nematic (TN) and vertically-aligned (VA) domains in the adjacent zones. A LC mixture comprised of nematic host, photopolymer and chiral material is initially filled into the VA cell with orthogonal rubbing treatment. After the ultraviolet irradiation on the filled LC cell through a photomask with Fresnel zone plate pattern, the interactions among orthogonal rubbing treatment, self-assembly polymer gravels, and chiral material induce the 90-TN structure in the odd zones, whereas the initial VA structures are maintained in the even zones.
View Article and Find Full Text PDFLiquid crystals (LCs) have been a vital component of modern communication and photonic technologies. However, traditional LC alignment on polyimide (PI) requires mechanically rubbing treatment to control LC orientation, suffering from dust particles, surface damage, and electrostatic charges. In this paper, LC alignment on organic single-crystal rubrene (SCR) has been studied and used to fabricate rubbing-free LC devices.
View Article and Find Full Text PDFIn this study, the response time of a 4 mm-aperture hole-patterned liquid crystal (HLC) lens has been significantly improved with doping of N-benzyl-2-methyl-4-nitroaniline (BNA) and rutile titanium dioxide nanoparticle (TiO NP) nanocomposite. The proposed HLC lens provides the focus and defocus times that are 8.5× and 14× faster than the pristine HLC lens, respectively.
View Article and Find Full Text PDFImprovements in electro-optical responses of LC devices by doping organic N-benzyl-2-methyl-4-nitroaniline (BNA) and Morpholinium 2-chloro-4-nitrobenzoate (M2C4N) in nematic liquid crystals (LCs) have been reported in this study. BNA and M2C4N-doped LC cells have the fall time that is fivefold and threefold faster than the pristine LC cell, respectively. The superior performance in fall time of BNA-doped LC cell is attributed to the significant decrements in the rotational viscosity and threshold voltage by 44% and 25%, respectively, and a strong additional restoring force resulted from the spontaneous polarization electric field of BNA.
View Article and Find Full Text PDFThe dispersion of organic N-benzyl-2-methyl-4-nitroaniline (BNA) in nematic liquid crystals (LCs) is studied. BNA doping decreases the threshold voltage of cell because of the reduced splay elastic constant and increased dielectric anisotropy of the LC mixture. When operated in the high voltage difference condition, the BNA-doped LC cell has a fall time that is five times faster than that of the pure one because of the decrements in the threshold voltage of the cell and rotational viscosity of the LC mixture.
View Article and Find Full Text PDFA 4 mm-aperture hole-patterned liquid crystal (LC) lens has been fabricated using a LC mixture, which consisted of rutile titanium dioxide (TiO) nanoparticles (NPs) and nematic LC E7, for the first time. The TiO NP dopant improves the addressing and operation voltages of the LC lens significantly because it strengthens the electric field surrounding the TiO NP and increases the capacitance of lens cell. Unlike the doping of common colloidal NPs, that of rutile TiO NPs increases the phase transition temperature and birefringence of the LC mixture, thereby helping enhance the lens power of LC lens.
View Article and Find Full Text PDFA novel approach for fabricating liquid crystal (LC) lenses is presented. The approach involves the use of a photocurable prepolymer dispersed in a cell fabricated with vertically aligned substrates. A radial gradient UV irradiation intensity distribution is produced using a radial variable neutral density filter.
View Article and Find Full Text PDFIn this study, a large-aperture hole-patterned liquid crystal (LHLC) lens was prepared from a mixture of nematic liquid crystal (NLC, E7) and organic material (N-benzyl-2-methyl-4-nitroaniline, BNA). The electro-optic properties of doped and undoped samples were measured, compared, and analyzed. The doped sample exhibited a response time that was ∼6 times faster than that of the undoped sample because BNA doping decreased the rotational viscosity of the NLC.
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