Silicon is a promising alternative to graphite anodes for achieving high-energy-density in lithium-ion batteries (LIBs) because of its high theoretical capacity (3579 mAh g). However, silicon anode must be developed to address its disadvantages, such as volume expansion and low electronic conductivity. Therefore, the use of silicon as composed with graphite and carbon anode materials is investigated, which requires properties such as a spherical morphology for high density and encapsulation of silicon particles in the composite.
View Article and Find Full Text PDFLiFePO emerges as a viable alternative to cobalt-containing cathodes, such as Li[Ni Mn Co ]O and Li[Ni Co Al ]O. As Fe is abundant in nature, LiFePO is a low-cost material. Moreover, stable structure of LiFePO imparts long service life and thermal stability.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2024
Lithium (Li) metal is considered an ultimate anode owing to its high specific capacity and energy density. However, uncontrolled Li dendrite growth and low Coulombic efficiency have limited the application of Li metal. Among various strategies introduced to address these limitations, the surface modification of polyolefin separators with functional materials has been widely adopted for improving the mechanical and thermal stabilities of polymer separators and to protect the separator from the penetration of Li dendrites.
View Article and Find Full Text PDFEngineering of solid electrolytes of Li-ion batteries is carried out for achieving high levels of ionic conductivity and preserving low levels of electrical conductivity. Doping metallic elements into solid electrolyte materials composed of Li, P, and O is quite challenging due to instances of possible decomposition and secondary phase formation. To accelerate the development of high-performance solid electrolytes, predictions of thermodynamic phase stabilities and conductivities are necessary, as they would avoid the need to carry out exhaustive trial-and-error experiments.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2022
Li metal has been intensively investigated as a next-generation rechargeable battery anode. However, its practical application as the anode material is hindered by the deposition of dendritic Li. To suppress dendritic Li growth, introducing a modified separator is considered an effective strategy since it promotes a uniform Li ion flux and strengthens thermal and mechanical stability.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2021
Silicon, as a promising next-generation anode material, has drawn special attention from industries due to its high theoretical capacity (around 3600 mAh g) in comparison with conventional electrodes, e.g., graphite.
View Article and Find Full Text PDFNanomaterials (Basel)
September 2021
Metallic Li has caught the attention of researchers studying future anodes for next-generation batteries, owing to its attractive properties: high theoretical capacity, highly negative standard potential, and very low density. However, inevitable issues, such as inhomogeneous Li deposition/dissolution and poor Coulombic efficiency, hinder the pragmatic use of Li anodes for commercial rechargeable batteries. As one of viable strategies, the surface functionalization of polymer separators has recently drawn significant attention from industries and academics to tackle the inherent issues of metallic Li anodes.
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