Electrospinning of Aqueous Solutions of Atactic Poly(-isopropylacrylamide) with Physical Gelation.

The phase diagram of a given polymer solution is used to determine the solution’s electrospinnability. We constructed a phase diagram of an aqueous solution of atactic poly(N-isopropylacrylamide) (a-PNIPAM) based on turbidity measurements and the rheological properties derived from linear viscoelasticity. Several important transition temperatures were obtained and discussed, including the onset temperature for concentration fluctuations T1, gel temperature Tgel, and binodal temperature Tb.