Correction for 'Mitigating substrate effects of van der Waals semiconductors using perfluoropolyether self-assembled monolayers' by Dae Young Park , , 2024, , 10779-10788, https://doi.org/10.1039/D4NR00061G.
View Article and Find Full Text PDFLocal deformation is a control knob to dynamically tune the electronic band structure of 2D semiconductors. This study demonstrates the local strain-dependent phonon properties of monolayer tungsten diselenide, which are investigated by using the scanning tunneling microscopy-based tip-enhanced Raman spectroscopy. The anomalous appearance and softening of the Raman-inactive out-of-plane mode are first revealed, which exhibits equivalent behavior to other principal phonons of tungsten diselenide.
View Article and Find Full Text PDFTransition metal dichalcogenide (TMDs) heterostructure, particularly the lateral heterostructure of two different TMDs, is gaining attention as ultrathin photonic devices based on the charge transfer (CT) excitons generated at the junction. However, the characteristics of the interface of the lateral heterostructure, determining the electronic band structure and alignment at the heterojunction region, have rarely been studied due to the limited spatial resolution of nondestructive analysis systems. In this study, we investigated the confined phonons resulting from the phonon-disorder scattering process involving multiple disorders at the lateral heterostructure interface of MoS-WS to prove the consequences of disorder-mediated deformation in the band structure.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Brightening dark excitons in transition metal dichalcogenide monolayers (MLs) can provide large-area ultrathin devices for applications in quantum information science and optoelectronics. For practical applications of dark excitons, a robust and bright emission over a wide area at room temperature is desirable; however, no reliable approach has been demonstrated thus far. In this study, an efficient approach is presented for brightening dark excitons at room temperature over a large area of a WSe ML via coupling between plasmons and dark excitons.
View Article and Find Full Text PDFRecently, 2D semiconductor-based optoelectronic memory has been explored to overcome the limitations of conventional von Neumann architectures by integrating optical sensing and data storage into one device. Persistent photocurrent (PPC), essential for optoelectronic memory, originates from charge carrier trapping according to the Shockley-Read-Hall (SRH) model in 2D semiconductors. The quasi-Fermi level position influences the activation of charge-trapping sites.
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