Publications by authors named "Frederique T H Broers"

This study examines Rembrandt's use of to depict the costume of Lieutenant Willem Van Ruytenburch, a prominently lit figure in (1642). As part of , the painting was analyzed using noninvasive imaging techniques, including reflectance imaging spectroscopy (RIS), macroscopic X-ray powder diffraction (MA-XRPD), and macroscopic X-ray fluorescence (MA-XRF). These methods enabled the mapping of the artist's pigment palette, which includes lead white, lead-tin yellow, ochres, vermilion, arsenic sulfide pigments, red lakes, smalt, and azurite.

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, one of the most famous masterpieces by Rembrandt, is the subject of a large research and conservation project. For the conservation treatment, it is of great importance to understand its current condition. Correlated nano-tomography using x-ray fluorescence and ptychography revealed a-so far unknown-lead-containing "layer", which likely acts as a protective impregnation layer applied on the canvas before the quartz-clay ground was applied.

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Article Synopsis
  • Paintings contain various chemical compounds that can degrade over time, significantly affecting their appearance.
  • The main focus of the study is on how the medium surrounding arsenic sulfide pigments, specifically orpiment, influences their degradation, revealing the formation of both arsenolite and arsenate species.
  • Results indicate that in the presence of a medium, As(V) species can migrate and react over time, causing structural stress in the paint and leading to visual changes like cracks or delamination.
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Among the artists' materials of the nineteenth century, pastel crayons merit scientific interest since their early commercial formulations are mostly unknown and, until now, have been considerably less studied with respect to other contemporary painting materials. In this framework, research herein reports the results of a comprehensive multi-analytical study of 44 pastel crayons of two recognized brands (LeFranc and Dr. F.

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