Publications by authors named "Eva Y Pfannerstill"

Cleaning activities can affect indoor air composition long after the cleaning is completed. Utilizing data from detailed observational monitoring campaigns, conducted over 21 weeks, we explore the influence of cleaning activities in two normally occupied, single-family houses. To study emissions and chemistry, we quantified more than 200 volatile organic compounds (VOCs) using a proton-transfer reaction time-of-flight mass spectrometer and 52 semivolatile organic compounds (SVOCs) using a semivolatile thermal-desorption gas chromatograph.

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In Los Angeles, air pollution disproportionately impacts communities of color and low-income residents. Routine city-wide measurements of hazardous air pollutants (HAPs), of concern for health and contributing to urban air pollution, are notably lacking. In this study, we use the highest spatially resolved (∼2 km) measurements of emissions and concentrations ever reported of HAPs while covering a whole megacity and combine observations with US Census information.

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In this study, we evaluate volatile chemical product (VCP; e.g., adhesives, personal care products) emissions in the McDonald et al.

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Despite decades of emission control measures aimed at improving air quality, Los Angeles (LA) continues to experience severe ozone pollution during the summertime. We incorporate cooking volatile organic compound (VOC) emissions in a chemical transport model and evaluate it against observations in order to improve the model representation of the present-day ozone chemical regime in LA. Using this updated model, we investigate the impact of adopting zero-emission vehicles (ZEVs) on ozone pollution with increased confidence.

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Article Synopsis
  • The decline in vehicle emissions highlights the increasing role of Volatile Organic Compounds (VOCs) from Volatile Chemical Products (VCP), but their complex chemistry poses challenges for accurate modeling.
  • Researchers developed a new chemical mechanism called RACM2B-VCP to better represent VOC emissions from VCP sources, specifically in urban settings like Los Angeles.
  • Model evaluations show promising results, indicating that over 50% of anthropogenic VOC reactivity and ozone enhancement in the area is linked to VCP emissions, despite some remaining discrepancies in the model's overall VOC reactivity predictions.
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Article Synopsis
  • Despite progress in reducing transportation emissions, urban areas in North America and Europe still deal with poor air quality, revealing new insights about sources of volatile organic compounds (VOCs).
  • Research in summer Los Angeles shows that biogenic terpenoids account for about 60% of VOC emissions affecting ozone and aerosol formation, with their impact rising with higher temperatures.
  • To effectively combat air pollution, especially ozone, it's crucial to control nitrogen oxides, as climate change will significantly alter both the quantity and type of VOC emissions.
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State inventories indicate that dairy operations account for nearly half of California's methane budget. Recent analyses suggest, however, that these emissions may be underestimated, complicating efforts to develop emission reduction strategies. Here, we report estimates of dairy methane emissions in the southern San Joaquin Valley (SJV) of California in June 2021 using airborne flux measurements.

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Article Synopsis
  • Los Angeles experiences significant air pollution from ozone and particulate matter, which hasn't improved much over the last ten years despite reduced emissions from vehicles.
  • Recent airborne measurements revealed a complex mix of volatile organic compounds (VOCs) in the area, with ethanol and terpenoids being the most prevalent sources.
  • Comparing these measurements with existing emission inventories highlighted inconsistencies in the data, especially concerning biogenic and volatile chemical product emissions, while transportation-related VOCs showed better alignment.
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Drought can affect the capacity of soils to emit and consume biogenic volatile organic compounds (VOCs). Here we show the impact of prolonged drought followed by rewetting and recovery on soil VOC fluxes in an experimental rainforest. Under wet conditions the rainforest soil acts as a net VOC sink, in particular for isoprenoids, carbonyls and alcohols.

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Drought impacts on microbial activity can alter soil carbon fate and lead to the loss of stored carbon to the atmosphere as CO and volatile organic compounds (VOCs). Here we examined drought impacts on carbon allocation by soil microbes in the Biosphere 2 artificial tropical rainforest by tracking C from position-specific C-pyruvate into CO and VOCs in parallel with multi-omics. During drought, efflux of C-enriched acetate, acetone and CHO (diacetyl) increased.

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