Can Organic Solar Cells Beat the Near-Equilibrium Thermodynamic Limit?

Despite an impressive increase over the past decade, experimentally determined power conversion efficiencies of organic photovoltaic cells still fall considerably below the theoretical upper bound for near-equilibrium solar cells. Even in otherwise optimized devices, a prominent yet incompletely understood loss channel is the thermalization of photogenerated charge carriers in the density of states that is broadened by energetic disorder. Here, we demonstrate by extensive numerical modeling how this loss channel can be mitigated in carefully designed morphologies.